The Gunnoe Research Group

Synthetic and Mechanistic Organometallic Chemistry at the University of Virginia

Publications

Patents: 

2. "Compositions and Methods for Single-Step Styrene Production" Gunnoe, T.B.; Vaughan, B.A.; Webster-Gardiner, M.S. US Provisional Patent Application No. 62/137,853.

1. "Compositions and Methods for Hydrocarbon Functionalization" PCT Application Serial No. PCT/US14/44272; filed June 26, 2014.

 

Edited Books: 

2. "The Changing Landscape of Hydrocarbon Feedstocks for Chemical Production: Implications for Catalysis" published based on a workshop (hosted by the National Academies of Sciences, Engineering and Medicine) by the National Academies Press, Workshop Planning Committee: Alexis T. Bell, Monty Alger, Maria Flytzani-Stephanopoulos, T. Brent Gunnoe, Johannes A. Lercher, and James C. Stevens.

1. "Catalytic Hydroarylation of Carbon-Carbon Multiple Bonds" Eds. Gunnoe, T. B., Ackermann, L., Habgood, L. G. Contract signed with Wiley-VCH to produce textbook. Targeted completion date is November 2017.

 

Book Chapters: 

3. "Introduction: Alkane C-H Activation by Single-Site Metal Catalysis" Gunnoe, T. B.* invited chapter in Alkane C-H Activation by Single-Site Metal Catalysis, 2012, Springer, Edited by Pedro J. Pérez, pp. 1-16.

2. "Metal-Mediated Carbon-Hydrogen Bond Activation" Gunnoe, T. B.* invited chapter in Physical Inorganic Chemistry: Reactions, Processes, and Applications, 2010, Wiley-VCH, Edited by A. Bakac, pp. 495-549.

1. "Ruthenium (II) and Iridium (III) Catalyzed Hydroarylation of Olefins" Gunnoe, T. B.*, Periana, R. A. invited chapter in Handbook of C-H Transformations, Volume 1, 2005, Wiley-VCH, Edited by G. Dyker, pp. 180-187.

 

Publications: 

135. "Studies of the Decomposition of the Ethylene Hydrophenylation Catalyst TpRu(CO)(NCMe)Ph" Joslin, E. E., McKeown, B. A., Cundari, T. R., Gunnoe, T. B.* Invited manuscript accepted J. Organomet. Chem. 2017 847, 289-293 (invited contribution to special issue dedicated to Professor John Gladysz "Organometallic Chemistry: from Stereochemistry to Catalysis to Nanochemistry"). https://doi.org/10.1016/j.jorganchem.2017.03.051.

134. "Catalytic synthesis of "super" linear alkenyl arenes using an easily prepared Rh(I) catalyst" Webster-Gardiner, M. S., Chen, J., Vaughan, B. A., McKeown, B. A., Schinski, W., Gunnoe, T. B.* J. Am. Chem. Soc. 2017 139, 5474-5480. DOI: 10.1021/jacs.7b01165. This manuscript was highlighted in Chemical and Engineering News 2017, 95(17), 8.

133. "Brønsted Acid-Catalyzed Intramolecular Hydroamination of Unactivated Alkenes: Metal Triflates as an in situ source of Triflic Acid" Chen, J., Goforth, S. K., McKeown, B. A., Gunnoe, T. B.* Dalton Transactions 2017, 46, 2884-2891. DOI: 10.1039/C6DT04710F

132. "Mechanistic Studies of Single-Step Styrene Production Using a Rhodium(I) Catalyst" Vaughan, B. A., Khani, S. K., Gary, J. B., Kammert, J. D., Webster-Gardiner, M. S.,  McKeown, B. A., Davis. R. J., Cundari, T. R.*, Gunnoe, T. B.* J. Am. Chem. Soc. 2017, 139, 1485-1498. DOI: 10.1021/jacs.6b10658

131. "Electrophilic RhI Catalysts for Arene C–H Activation: Electrophilic Aromatic Substitution Mechanism" Webster-Gardiner, M. S., Piszel, P. E., Fu, R., McKeown, B. A., Nielsen, R. J., Goddard III, W. A.*, Gunnoe, T. B.* J. Mol. Catal. 2017, 426, 381-388 (special issue "C–H Functionalization in Modern Molecular Catalysis" dedicated to Professor Georgiy B. Shul’pin). DOI: doi.org/10.1016/j.molcata.2016.07.045

130. "Aerobic Epoxidation of Olefin by Platinum Catalysts Supported on Mesoporous Silica Nanoparticles" Munz, D., Wang, D., Moyer, M. M., Webster-Gardiner, M. S., Kunal, P., Watts, D., Trewyn, B. G.*, Vedernikov, A. N.*, Gunnoe, T. B.* ACS Catalysis 2016, 6, 4584–4593. DOI: 10.1021/acscatal.6b01532

129. "Transition-Metal-Mediated Nucleophilic Aromatic Substitution with Acids" O'Reilly, M. A., Johnson, S. I., Nielsen, R. J., Goddard III, W. A.*, Gunnoe, T. B.* Organometallics 2016, 35, 2053-2056.135. DOI: 10.1021/acs.organomet.6b00285  

128.  "Combined Furan C–H Activation and Furyl Ring-Opening by an Iron(II) Complex" Taylor, K. H., Kalman, S. E., Gunnoe, T. B.*, Sabat, M. Organometallics, 2016, 2296-2311 DOI.org/10.1021/acs.organomet.6b00276

127. "Transition Metal Mediated C–H Activation and Functionalization: The Role of Poly(pyrazolyl)borate and Poly(pyrazolyl)alkane Ligands" McKeown, B. A., Lee, J. P., Mei, J. J., Cundari, T. R., Gunnoe, T. B.* Eur. J. Inorg. Chem. 2016, 2296-2311 (special issue "The Significance of Scorpionate Ligands 50 Years on"). DOI: 10.1002/ejic.201501470

126. "MAXNET Energy - Focusing Research in Chemical Energy Conversion on the Electrocatalytic Oxygen Evolution" Auer, A. A., Antonietti, M., Antonyshyn, I., Böhm, K.-H., Brüller, S., Cap, S., Cherevko, S., Davis, R. J., Deng, X., Fellinger, T., Freakley, S., Grin, Y., Gunnoe, T. B., Haj-Hariri, H., Hutchings, G., Liang, H., Mayrhofer, K. J. J., Müllen, K., Neese, F., Papakonstantinou, G., Ranjan, C., Sankar, M., Schlögl, R., Schüth, F., Shalom, M., Spanos, I., Stratmann, M., Sundmacher, K., Tüysüz, H., Vidakovic-Koch, T., Yi, Y., Zangari, G. Green 2015, 5, 7-21. DOI.org/ 10.1515/green-2015-0021

125. "Platinum-based Single-Site Catalysts Tethered onto Ordered Mesoporous Carbon as Active Electrocatalysts for Low Temperature Direct Methane Fuel Cells" Joglekar, M., Nguyen, V., Pylypenko, S., Li, Q., O'Reilly, M. A., Gray, T. S., Gunnoe, T. B.*, Herring, A. M.*, Trewyn, B. G.*J. Am. Chem. Soc. 2015137, 116-125 (work was highlighted in Chemical and Engineering News, selected as a cover feature and highlighted in JACS Spotlights) DOI.org/10.1021/jacs.5b6392

124. "A Meeting of Metals–A Joint Virtual Issue between Organometallics and ACS Catalysis on First-Row Transition Metal Complexes" Chirik, P. J., Gunnoe, T. B. Editorial, ACS Catalysis 20155, 5584-5585 (not peer reviewed) DOI.org/10.1021/acscatal.5b01831

123. "A Rhodium Catalyst for Single-Step Styrene Production" Vaughan, B. A., Webster-Gardiner, M. S., Cundari, T. R.*, Gunnoe, T. B.* Science 2015348, 421-424. This manuscript was highlighted in Chemical and Engineering News 201593 (17), 26 and Phys.org. DOI.org/10.1126/science.aaa2260

122. "Phosphine and N-Heterocyclic Carbene Ligands on Pt(II) Shift Selectivity from Ethylene Hydrophenylation toward Benzene Vinylation" Brosnahan, A. M., Talbot, A., McKeown, B. A., Kalman, S. E., Gunnoe, T. B.*, Ess, D. H.*, Sabat, M. Manuscript accepted J. Organomet. Chem. 2015  (invited contribution for special issue in memoriam of Alexander E. Shilov) DOI.org/10.1016/j.jorganchem.2015.03.019

121. "Partial Oxidation of Light Hydrocarbons by Periodate and Chloride Salts" Kalman, S. E., Munz, D., Fortman, G. C., Boaz, N. C., Groves, J. T.*, Gunnoe, T. B.* Dalton Trans. 2015 44, 5294-5298. DOI.org/10.1039/C5DT00558B

120. "Synthesis of RhIII Anilido, Hydroxide, and Methoxide Complexes" Burgess, S. A., Bolaño, T.,  Gunnoe, T. B.*, Sabat, M., Myers, W. H. Eur. J. Inorg. Chem. 2015 1041-1052. DOI.org/10.1002/ejic.201403147

119. "Proton or Metal? The H/D Exchange of Aromatics in Acidic Solvents" Munz, D., Webster-Gardiner, M. S., Fu R., Strassner, T., Goddard III, W. A.*, Gunnoe, T. B.* ACS Catalysis 20155, 769-775. DOI.org/10.1021/cs501620f

118. "Rhodium Bis(quinolinyl)benzene Complexes for Methane Activation and Functionalization" Fu, R., O'Reilly, M. E., Nielsen, R. J., Goddard III, W. A.*, Gunnoe, T. B.* Chem. Eur. J. 201521, 1286-1293. DOI.org/10.1002/chem.201405460

117. "Arene C–H Activation using Rh(I) Catalysts Supported by Bidentate Nitrogen Chelates" Webster-Gardiner, M. S., Fu, R., Fortman, G. C., Nielsen, R. J., Gunnoe, T. B.*, Goddard III, W. A.* Cat. Sci. Tech. 20155, 96-100 (invited contribution to "Catalysis in the USA" issue). DOI.org/10.1039/C4CY00972J

116. "Reductive Functionalization of a Rhodium(III)-methyl Bond in Acidic Media: A Key Step in Methane Electrophilic Functionalization" O'Reilly, M. E., Pahls, D. R., Cundari, T. R.*, Gunnoe, T. B.* Organometallics 201433, 6504-6510. DOI.org/10.1039/C4DT00234B

115. "DFT Virtual Screening Identifies Rhodium-Amidinate Complexes As Potential Homogeneous Catalysts for Methane to Methanol Oxidation" Fu, R., Nielsen, R.*, Goddard III, W. A.*, Fortman, G., Gunnoe, T. B.* ACS Catalysis 20144, 4455-4465. DOI.org/10.1021/cs5005322

114. "Long Range C–H Bond Activation by RhIII-carboxylates" O'Reilly, M. E., Fu, R., Nielsen, R. J., Sabat, M., Goddard III, W. A.*, Gunnoe, T. B.* J. Am. Chem. Soc. 2014136, 14690-14693. DOI.org/10.1021/ja508367m

113. "Metal-Free Amidation of Ether sp3 C–H Bonds with Sulfonamides using PhI(OAc)2" Campos, J., Goforth, S. K., Crabtree, R. H.*, Gunnoe, T. B.* RSC Adv. 20144, 47951-47957. DOI.org/10.1039/C4RA09665G

112. "Oxygen Atom Insertion into Iron(II) Phenyl and Methyl Bonds: A Key Step for Catalytic Hydrocarbon Functionalization" Mei, J., Pardue, D. B., Kalman, S. E., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M. Organometallics 201433, 5597-5605. DOI.org/10.1021/om500914h

111. "Formation of Hydroxyindenyl and Vinylidene Ligands by Reaction of Internal Alkynes with Cp*Fe(CO)(NCMe)Ph" Kalman, S. E., Gunnoe, T. B.*, Sabat, M. Organometallics 201433, 5457-5463. DOI.org/10.1021/om500748v

110. "Polymers for the stabilization and delivery of proteins topically and per os to the insect hemocoel through conjugation with aliphatic polyethylene glycol" Jeffers, L. A., Shen, H., Bissinger, B. W., Khalil, S., Gunnoe, T. B., Roe, R. M. Pest. Biol. Phys. 2014115, 58-66. DOI.org/10.1016/j.pestbp.2014.08.006

109. "Selective CH Functionalization of Methane, Ethane and Propane by a Perfluoroarene Iodine(III) Complex" Konnick, M. M., Hashiguchi, B. G., Devarajan, D., Boaz, N. C., Gunnoe, T. B., Groves, J. T., Ess, D. H., Periana, R. A. Angew. Chem. Int. Ed. 201453, 10490-10494. DOI.org/10.1002/anie.201406185

108. "Hydrophenylation of Ethylene using a Cationic Ru(II) Catalyst: Comparison to a Neutral Ru(II) Catalyst" Burgess, S. A., Joslin, E. E., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M., Myers, W. H. Chem. Sci.  20145, 4355-4366. DOI.org/10.1039/C4SC01665C

107. "C–H Activation of Pyrazolyl Ligands by Ru(II)" Joslin, E. E., Quillian, B., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M., Myers, W. H. Inorg. Chem. 201453, 6270-6279. DOI.org/10.1021/ic500811n

106. "Selective Monooxidation of Light Alkanes Using Chloride and Iodate" Fortman, G. C., Boaz, N. C., Munz, D., Konnick, M. M., Periana, R. A., Groves, J. T.*, Gunnoe, T. B.* J. Am. Chem. Soc. 2014136, 8393-8401. This work was highlighted in Chemical and Engineering News 2014,92 (33), 23-24. DOI.org/10.1021/ja502657g

105. "1,2-Addition of Dihydrogen across Rh(III)–OMe Bonds" Burgess, S. A., Devarajan, D., Bolaño, T., Ess, D. H.*, Gunnoe, T. B.*, Sabat, M., Myers, W. H. Inorg. Chem. 201453, 5328–5340. DOI.org/10.1021/ic500636m

104. "Pt(II) Catalyzed Hydrophenylation of a-Olefins: Variation of Linear/Branched Products as a Function of Ligand Donor Ability" McKeown, B. A., Prince, B. M., Ramiro, Z., Gunnoe, T. B.*, Cundari, T. R.* ACS Catalysis 20144, 1607-1615. DOI.org/10.1021/cs400988w

103. "Theoretical Study of Reductive Functionalization of Methyl Ligands of Group 9 Complexes Supported by Two Bipyridyl Ligands: A Key Step in Catalytic Hydrocarbon Functionalization" Pahls, D. R., Groves, J. T., Gunnoe, T. B., Cundari, T.R.* Organometallics 201433, 1936-1944. DOI.org/10.1021/om4010093

102. "Reductive Functionalization of a Rh(III)-methyl Bond by Electronic Modification of the Supporting Ligand" O'Reilly, M. E., Pahls, D. R., Webb, J. R., Boaz, N. C., Majumdar, S., Hoff, C. D., Groves, J. T.*, Cundari, T. R.*, Gunnoe, T. B.* Dalton Trans. 201443, 8273-8281. DOI.org/10.1021/om5008456

101. "Oxy-functionalization of Group 9 and 10 Transition Metal Methyl Ligands: Use of Pyridine-based Hemi-labile Ligands" Prince, B. M., Gunnoe, T. B.*, Cundari, T. R.* Dalton Trans. 201443, 7608-7614. DOI.org/10.1039/C4DT00371C

100. "DFT Study of Oxygen Atom Insertion into Metal–Methyl Bonds of Fe(II), Ru(II) and Os(II) Complexes: Study of Metal-Mediated C–O Bond Formation" Pardue, D. B., Mei, J. J., Cundari, T. R.*, Gunnoe, T. B.* Inorg. Chem. 201453, 2968–2975. DOI.org/10.1021/ic402759w

99. "Activation of Carbon-Hydrogen Bonds and Dihydrogen by 1,2-CH-Addition across Metal-Heteroatom Bonds" Webb, J. R., Burgess, S. A., Cundari, T. R.*, Gunnoe, T. B.* Dalton Trans. 2013 42, 16646-16665. DOI.org/10.1039/C3DT52164H

98. "Control of Olefin Hydroarylation Catalysis via a Sterically and Electronically Flexible PtII Catalyst Scaffold" McKeown, B. A., Gonzalez, H. E., Michaelos, T., Gunnoe, T. B.*, Cundari, T. R.*, Crabtree, R. H., Sabat, M. Organometallics 2013, 32, 3903-3913. DOI.org/10.1021/om400390e

97. "Pt(II) and Rh(III) Hydrocarbyl Complexes Bearing Coordinated Oxygen Atom Delivery Reagents" Webb, J. R., Figg, T. M., Otten, B. M., Cundari, T. R.*, Gunnoe, T. B.*, Sabat, M. Eur. J. Inorg. Chem. 2013, 4515-4525. DOI.org/10.1002/ejic.201300434

96. "PtII Catalyzed Ethylene Hydrophenylation: Influence of Dipyridyl Chelate Ring Size on Catalyst Activity and Longevity" McKeown, B. A., Gonzalez, H. E., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M. ACS Catalysis 20133, 1165–1171. DOI.org/10.1021/cs400231f

95. "PtII Catalyzed Ethylene Hydrophenylation: Switching Selectivity between Alkyl and Vinyl Benzene Production" McKeown, B. A., Gonzalez, H. E., Friedfeld, M. R., Brosnahan, A. M., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M. Organometallics 2013, 32, 2857-2865. DOI.org/10.1021/om400306w

94. "Facile and Regioselective C–H Bond Activation of Aromatic Substrates by an Fe(II) Complex Involving a Spin-Forbidden Pathway" Kalman, S. E., Petit, A., Gunnoe, T. B.*, Ess, D. H.*, Cundari, T. R.*, Sabat, M. Organometallics 201332, 1797-1806. DOI.org/10.1021/om301219t

93. "2,2,2-Tris(pyrazolyl)ethoxide (Epox) Ruthenium (II) Complexes, (Epox)RuCl(L)(L'): Synthesis, Structure and Reactivity" Quillian, B., Joslin, E. E., Gunnoe, T. B.*, Sabat, M. Inorg. Chem. 201352, 1113-1121. DOI.org/10.1021/ic3024474

92. "Variable Pathways for Oxygen Atom Insertion into Metal–Carbon Bonds: The Case of Cp*W(O)2(CH2SiMe3)" Mei, J., Carsch, K. M., Freitag, C. R., Gunnoe, T. B.*, Cundari, T. R.* J. Am. Chem. Soc. 2013135, 424-435. DOI.org/10.1021/ja309755g

91. "Direct Coupling of Nitriles and Aniline to Form the Triazapentadience Species Rh(III){NH=C(R)N(Ph)C(R)=NH}" Bolaño, T., Gunnoe, T. B.*, Sabat, M. Dalton Trans. 201342, 347-350. DOI.org/10.1039/C2DT32606J

90. "Intramolecular Hydroalkoxylation and Hydroamination of Alkynes Catalyzed by Cu(I) Complexes Supported by N-Heterocyclic Carbene Ligands" Pouy, M. J., Delp, S. A., Uddin, J., Ramdeen, V. M., Cochrane, N. A., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M., Myers, W. H. ACS Catalysis 20122, 2182-2193. DOI.org/10.1021/cs300544w

89. "Catalytic Hydroarylation of Ethylene using TpRu(L)(NCMe)Ph (L = 2,6,7-Trioxa-1-phosphabicyclo[2,2,1]heptane): Comparison to TpRu(L')(NCMe)Ph Systems (L' = CO, PMe3 or P(OCH2)3CEt)" Joslin, E. E., McMullin, C. L., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M., Myers, W. H.Organometallics 201231, 6851-6860. DOI.org/10.1021/om300676e

88. "Flavin-Catalyzed Insertion of Oxygen into Rhenium-Methyl Bonds" Pouy, M. J., Milczek, E. M., Figg, T. M., Otten, B. M., Prince, B. M., Gunnoe, T. B.*, Cundari, T. R.*, Groves, J. T.* J. Am. Chem. Soc. 2012134, 12920-12923. DOI.org/10.1021/ja3054139

87. "Theory of Late-Transition-Metal Alkyl and Heteroatom Bonding: Analysis of Pt, Ru, Ir, and Rh Complexes" Devarajan, D., Gunnoe, T. B., Ess, D. H.* Inorg. Chem. 201251, 6710–6718. DOI.org/10.1021/ic300350k

86. "Coordination Chemistry of 4-Methyl-2,6,7-Trioxa-1-phosphabicyclo[2,2,1]heptane: Preparation and Characterization of Ru(II) Complexes" Joslin, E. E., McMullin, C. L., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M. Inorg. Chem. 201251, 4791-4801. DOI.org/10.1021/ic300109b

85. "The Para-Substituent Effect and pH-dependence of the Organometallic Baeyer-Villiger Oxidation of Rhenium-Carbon Bonds" Cheng, M.-J., Bischof, S. M., Nielsen, R. J.*, Goddard III, W. A., Gunnoe, T. B., Periana, R. A. Dalton Trans. 201241, 3758-3763. DOI.org/10.1039/C2DT11984F

84. "Carbon–Oxygen Bond Formation via Organometallic Baeyer–Villiger Transformations: A Computational Study on the Impact of Metal Identity" Figg, T. M., Webb, J. R., Cundari, T. R.*, Gunnoe, T. B.* J. Am. Chem. Soc. 2012, 134, 2332-2339. DOI.org/10.1021/ja2102778

83. "Enhanced Activity of an Insecticidal Protein, Trypsin Modulating Oostatic Factor (TMOF), through Conjugation with Aliphatic Poly(ethylene glycol)" Jeffers, L. A., Shen, H.-Y., Khalil, S., Bissinger, B. W., Brandt, A., Gunnoe, T. B.*, Roe, R. M.* Pest Manag. Sci. 201268, 49-59. DOI.org/10.1002/ps.2219

82. "DFT Study of Group 8 Catalysts for the Hydrophenylation of Ethylene: Influence of Ancillary Ligands and Metal Identity" Morello, G. R., Cundari, T. R.*, Gunnoe, T. B.* J. Organomet. Chem. 2012697, 15-22.  DOI.org/10.1016/j.jorganchem.2011.09.019

81. "Mechanistic Studies of Ethylene Hydrophenylation Catalyzed by Bipyridyl Pt(II) Complexes" McKeown, B. A., Gonzalez, H. E., Friedfeld, M. R., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M. J. Am. Chem. Soc. 2011133, 19131-19152. DOI.org/10.1021/ja206064v

80. "Non-Redox Oxy-Insertion via Organometallic Baeyer-Villiger Transformations: A Computational Hammett Study of Platinum(II) Complexes" Figg, T. M., Cundari, T. R.*, Gunnoe, T. B.* Organometallics 201130, 3779-3785. DOI.org/10.1021/om200258d

79. "Hyper-Distorted Tungsten Allyl Complexes and their Stereoselective Deprotonation to Form Dihapto-Coordinated Dienes" Harrison, D. P., Nichols-Nielander, A. C., Zottig, V. E., Strausberg, L. J., Salomon, R. J., Trindle, C. O., Sabat, M., Gunnoe, T. B., Iovan, D. A., Myers, W. H., Harman, W. D.* Organometallics 201130, 2587-2597. DOI.org/10.1021/om200183m

78. "Pt(II) and Pt(IV) Amido, Aryloxo, and Hydrocarbyl Complexes: Synthesis, Characterization, and Reaction with Dihydrogen and Substrates that Possess C-H Bonds" Webb, J. R., Munro-Leighton, C., Pierpont, A. W., Gurkin, J. T., Gunnoe, T. B.*, Cundari, T. R.*, Sabat, M., Petersen, J. L., Boyle, P. D. Inorg. Chem. 201150, 4195-4211 (manuscript featured on cover). DOI.org/10.1021/ic200153n

77. "Functionalization of Rhenium Aryl Bonds by O-Atom Transfer" Bischof, S. M., Chen, M.-J., Nielsen, R. J., Gunnoe, T. B., Goddard, III, W. A., Periana, R. A.* Organometallics 201130, 2079-2082. DOI.org/10.1021/om2002365

76. "Chemistry in the Center for Catalytic Hydrocarbon Functionalization: An Energy Frontier Research Center" Golisz, S. R., Gunnoe, T. B., Goddard, III, W. A., Groves, J. T., Periana, R. A. Cat. Lett. 2011141, 213-221. DOI.org/10.1007/s10562-010-0499-5

75. "Well-Defined Cu(I) Amido Complex with Aryl Iodides Reacting to Form Aryl Amines" Delp, S. A., Goj, L. A., Munro-Leighton, C., Lee, J. P., Gunnoe, T. B.*, Cundari, T. R.*, Petersen, J. L. Organometallics 201130, 55-57. DOI.org/10.1021/om101084e

74. "Catalytic Oxy-Functionalization of Methane and Other Hydrocarbons: New Fundamental Advancements and Strategies" Webb, J. A., Bolaño, T., Gunnoe, T. B.* Invited manuscript accepted for publication in ChemSusChem 20114, 37-49 (manuscript featured on cover and was one of the 25 "most-accessed" manuscripts for 2011). DOI.org/10.1002/cssc.201000319

73. "Transition Metal Catalyzed Hydroarylation of Olefins using Unactivated Substrates:  Recent Developments and Challenges" Andreatta, J. R., McKeown, B. A., Gunnoe, T. B.* J. Organomet. Chem. 2011696, 305-315 (invited review). DOI.org/10.1016/j.jorganchem.2010.09.030

72. "Ligand Lone-Pair Influence on Hydrocarbon C-H Activation: A Computational Perspective" Ess, D. H.*, Gunnoe, T. B.*, Cundari, T. R.*, Goddard III, W. A., Periana, R. A., Organometallics 2010, 29, 6801-6815. DOI.org/10.1021/om100974q

71. "Net Hydrogenation of Pt-NHPh Bond is Catalyzed by Elemental Pt" Webb, J. R., Pierpont, A. W., Munro-Leighton, C., Gunnoe, T. B.*, Cundari, T. R.*, Boyle, P. D. J. Am. Chem. Soc. 2010132, 4520-4521. DOI.org/10.1021/ja9102309

70. "Invisible Proteins: Novel Delivery System for the Stabilization and Enhanced Activity of Protein Insecticides" Roe, R. M.*, Jeffers, L. A., Bissinger, B. E., Shen, H.-Y., Gunnoe, T. B.*, Brandt, A. Proceedings of the Beltwide Cotton Conferences, January 5-8, 2009, 834-843.

69. "Ru(II) Catalysts Supported by Hydridotris(pyrazolyl)borate for the Hydroarylation of Olefins: Reaction Scope, Mechanistic Studies and Guides for the Development of Improved Catalysts" Foley, N. A., Lee, J. P., Gunnoe, T. B.*, Cundari, T. R.* Acc. Chem. Res. 200942, 585-597. DOI.org/10.1021/ar800183j

68. "Novel Insecticide Polymer Chemistry to Reduce the Enzymatic Digestion of a Protein Pesticide, Trypsin Modulating Oostatic Factor (TMOF)" Shen, H.-Y., Brandt, A., Witting-Bissinger, B. E., Gunnoe, T. B.*, Roe, R. M.* Manuscript Pestic. Biochem. Physiol. 200993, 144-152. DOI.org/10.1016/j.pestbp.2009.02.004

67. "Six-, Five- and Four-Coordinate Ruthenium(II) Hydride Complexes Supported by N-Heterocyclic Carbene Ligands: Synthesis, Characterization, Fundamental Reactivity and Catalytic Hydrogenation of Olefins, Aldehydes and Ketones" Lee, J. P., Ke, Z.,  Ramírez, M. A., Gunnoe, T. B.*, Cundari, T. R.*, Boyle, P. D., Petersen, J. L. Organometallics 2009, 28, 1758-1775. DOI.org/10.1021/om801111c

66. "Combined Experimental and Computational Study of W(II), Ru(II), Pt(IV) and Cu(I) Amine and Amido Complexes Using 15N NMR Spectroscopy" Delp, S. A., Munro-Leighton, C., Khosla, C., Templeton, J. L., Alsop, N. M., Gunnoe, T. B.*, Cundari, T. R.* J. Organomet. Chem.2009694, 1549-1556. DOI.org/10.1016/j.jorganchem.2009.01.006

65. "Chlorination of Boron on a Ruthenium Coordinated Hydridotris(pyrazolyl)borate (Tp) Ligand: A Caveat for the Use of TpRu(PPh3)2Cl" Foley, N. A., Abernethy, R. J., Gunnoe, T. B.*, Hill, A. F., Boyle, P. D., Sabat, M. Organometallics 200928, 374-377. DOI.org/10.1021/om8008074

64. "Hydroarylation of Unactivated Olefins Catalyzed by Pt(II) Complexes" McKeown, B. A., Foley, N. A., Lee, J. P., Gunnoe, T. B.* Organometallics 200827, 4031-4033. DOI.org/10.1021/om8006008

63. "Preparation and Reactivity of a Well-Defined Monomeric Octahedral Pt(IV) Amido Complex" Munro-Leighton, C., Feng, Y., Zhang, J. Alsop, N. M., Gunnoe, T. B.*, Boyle, P. D., Petersen, J. L. Inorg. Chem. 200847, 6124-6126. DOI.org/10.1021/ic800843b

62. "Ruthenium (II) Complexes Possessing the h6-p-Cymene Ligand" Sumiyoshi, T., Gunnoe, T. B.* Petersen, J. L., Boyle, P. D. Inorg. Chim. Acta 2008361, 3254-3262 (special issue in honor of Professor Robert Angelici) DOI.org/10.1016/j.ica.2007.10.012

61. "Aromatic C-H Activation and Hydrophenylation of Ethylene by TpRu{P(OCH2)3CEt}(NCMe)Ph" Foley, N. A., Ke, Z., Gunnoe, T. B.*, Cundari, T. R.*, Petersen, J. L. Organometallics 200827, 3007-3017. DOI.org/10.1021/om800275b

60. "Chemistry Surrounding Group VII Complexes that Possess Poly(pyrazolyl)borate Ligands" Lail, M., Pittard, K. A., Gunnoe, T. B.* Adv. Organomet. Chem. 200856, 95-153. DOI.org/10.1016/S0065-3055(07)56002-8

59. "Activation of sp3 Carbon-Hydrogen Bonds by a Ru(II) Complex and Subsequent Metal-Mediated C-C and C-N Bond Formation" Foley, N. A., Gunnoe, T. B.*, Cundari, T. R.*, Boyle, P. D., Petersen, J. L. Angew. Chem. Int. Ed. 200847, 726-730 (selected as an Angew. Chem. "hot" paper) DOI.org/10.1002/anie.200704614

58. "Anti-Markovnikov Hydroamination and Hydrothiolation of Vinylarenes Catalyzed by Well-Defined Monomeric Copper(I) Amido and Thiolate Complexes" Munro-Leighton, C., Delp, S. A., Alsop, N. M., Blue, E. D., Gunnoe, T. B.* Chem. Commun. 2008, 111-113. DOI.org/10.1039/B715507G

57. "Combined Experimental and Computational Studies on the Nature of Aromatic C-H Activation by Octahedral Ru(II) Complexes:  Evidence for s-Bond Metathesis from Hammett Studies" DeYonker, N. J., Foley, N. A., Cundari, T. R.*, Gunnoe, T. B.* Organometallics 200726, 6604-6611. DOI.org/10.1021/om7009057

56. "Combined Experimental and Computational Study of TpRu{P(pyr)3}(NCMe)Me (pyr = N-pyrrolyl):  Inter- and Intramolecular Activation of C-H Bonds and the Impact of Sterics on Catalytic Hydroarylation of Olefins" Foley, N. A., Lail, M., Gunnoe, T. B.*, Cundari, T. R.*, Boyle, P. D., Petersen, J. L. Organometallics 200726, 5507-5516. DOI.org/10.1021/om700666y

55. "Activation of Carbon-Hydrogen Bonds via 1,2-Addition across M-X (X = OH or NH2) Bonds of d6 Transition Metals as a Potential Key Step in Hydrocarbon Functionalization: A Computational Study" Cundari, T. R.*, Grimes, T., Gunnoe, T. B.* J. Am. Chem. Soc. 2007129, 13172-13182. DOI.org/10.1021/ja074125g

54. "Comparative Reactivity of TpRu(L)(NCMe)Ph (L = CO or PMe3):  Impact of Ancillary Ligand L on Activation of Carbon-Hydrogen Bonds including Catalytic Hydroarylation and Hydrovinylation/Oligomerization of Ethylene" Foley, N. A., Lail, M., Gunnoe, T. B.*, Cundari, T. R., Petersen, J. L. J. Am. Chem. Soc. 2007129, 6765-6781. DOI.org/10.1021/ja068542p

53. "Reactivity of TpRu(L)(NCMe)R (L = CO, PMe3; R = Me, Ph) Systems with Isonitriles:  Experimental and Computational Studies Toward the Intra- and Intermolecular Hydroarylation of Isonitriles" Lee, J. P., Jimenez-Halla, J. O. C., Cundari, T. R.*, Gunnoe T. B.* J. Organomet. Chem.2007692, 2175-2186. DOI.org/10.1016/j.jorganchem.2007.01.037

52. "Addition of S-H Bonds across Electron-Deficient Olefins Catalyzed by Well-Defined Copper(I) Thiolate Complexes" Delp, S. A., Munro-Leighton, C., Goj, L. A., Ramírez, M. A., Gunnoe, T. B.*, Petersen, J. L. Inorg. Chem. 200746, 2365-2367. DOI.org/10.1021/ic070268s

51. "Reactivity of Ruthenium (II) and Copper (I) Complexes that Possess Anionic Heteroatomic Ligands:  Synthetic Exploitation of Nucleophilicity and Basicity of Amido, Hydroxo, Alkoxo and Aryloxo Ligands for the Activation of Substrates that Possess Polar Bonds as Well as Non-Polar C-H and H-H Bonds" Gunnoe, T. B.* (Invited micro-review, work featured on cover) Eur. J. Inorg. Chem. 2007, 1185-1203. DOI.org/10.1002/ejic.200601072

50. "Addition of N-H and O-H Bonds of Amines and Alcohols to Electron-Deficient Olefins Catalyzed by Monomeric Copper(I) Systems: Reaction Scope, Mechanistic Details and Comparison of Catalyst Efficiency" Munro-Leighton, C., Delp, S. A., Blue, E. D., Gunnoe, T. B.* Organometallics 200726, 1483-1493 (15th most-accessed manuscript for 2007). DOI.org/10.1021/om061133h

49. "Protonation of N-Heterocyclic Carbene Ligand Coordinated to Copper(I): Coordination Mode of Imidazolium Cation as a Function of Counterion as Determined by Solid-State Structures" Blue, E. D., Gunnoe, T. B.*, Petersen, J. L., Boyle, P. D. J. Organomet. Chem. 2006691, 6000-6005. DOI.org/10.1016/j.jorganchem.2006.09.051

48. "Chemistry Surrounding Monomeric Cu(I) Methyl, Phenyl, Anilido, Ethoxide and Phenoxide Complexes Supported by N-Heterocyclic Carbene Ligands: Reactivity Consistent with both Early and Late Transition Metal Systems" Goj, L. A., Blue, E. D., Delp, S. A., Gunnoe, T. B.*, Cundari, T. R., Pierpont, A. W., Petersen, J. L., Inorg. Chem. 200645, 9032-9045. DOI.org/10.1021/ic0611995

47. "Octahedral [TpRu(PMe3)2OR]n+ Complexes (Tp = hydridotris(pyrazolyl)borate; R = H or Ph; n = 0 or 1): Reactions at Ru(II) and Ru(III) Oxidation States with Carbon-Hydrogen Bonds" Feng, Y., Gunnoe, T. B.*, Cundari, T. R. Organometallics 200625, 5456-5465. DOI.org/10.1021/om0606385

46. "Single-Electron Oxidation of Monomeric Copper (I) Alkyl Complexes:  Evidence for Reductive Elimination through Bimolecular Formation of Alkanes" Goj, L. A., Blue, E. D., Delp, S. A. Gunnoe, T. B.*, Cundari, T. R.*, Petersen, J. L. Organometallics 200625, 4097-4104. DOI.org/10.1021/om060409i

45. "Hydrogen-Deuterium Exchange between TpRu(PMe3)(L)X (Tp = hydridotris(pyrazolyl)borate; L = PMe3 and X = OH, OPh, Me, Ph, or NHPh; L = NCMe and X = Ph) and Deuterated Arene Solvents:  Evidence for Metal-Mediated Processes" Feng, Y., Lail, M., Foley, N. A., Gunnoe, T. B.*, Barakat, K. A., Cundari, T. R., Petersen, J. L. J. Am. Chem. Soc. 2006128, 7982-7994. DOI.org/10.1021/ja0615775

44. "Reactions of a Ru(II) Phenyl Complex with Substrates that Possess C-N or C-O Multiple Bonds:  C-C Bond Formation, N-H Bond Cleavage and Decarbonylation Reactions" Lee, J. P., Pittard, K. A., Cundari, T. R., Gunnoe, T. B.*, Petersen, J. L. Organometallics 200625, 1500-1510. DOI.org/10.1021/om050967h

43. "Reactions of TpRu(CO)(NCMe)(Ph) (Tp = hydridotris(pyrazolyl)borate) with Electron-Rich Olefins:  Examples of Stoichiometric C-S and C-H Bond Cleavage" Goj, L. A., Lail, M., Pittard, K. A., Riley, K. C., Gunnoe, T. B.*, Petersen, J. L. Chem. Commun. 2006, 982-984. DOI.org/10.1021/om049508r

42. "Anti-Markovnikov N-H and O-H Additions to Electron-Deficient Olefins Catalyzed by Well-Defined Cu(I) Anilido, Ethoxide and Phenoxide Systems" Munro-Leighton, C., Blue, E. D., Gunnoe, T. B.* J. Am. Chem. Soc. 2006128, 1446-1447. DOI.org/10.1021/ja057622a

41. "Cleavage of X-H Bonds (X = N, O, or C) by Cu(I) Alkyl Complexes to Form Monomeric Two-Coordinate Cu(I) Systems" Goj, L. A., Blue, E. D., Munro-Leighton, C., Gunnoe, T. B.*, Petersen, J. L. Inorg. Chem. 200544, 8647-8649. DOI.org/10.1021/ic0517624

40. "Synthesis of the Five-Coordinate Ruthenium(II) Complexes [(PCP)Ru(CO)(L)][BAr'4] (PCP = 2,6-(CH2PtBu2)2C6H3, BAr'4 = 2,6-(CF3)2C6H3, L = h1-ClCH2Cl, h1-N2, or m-Cl-Ru(PCP)(CO)): Reactions with Phenyldiazomethane and Phenylacetylene"  Zhang, J., Barakat, K. A., Cundari, T. R., Gunnoe, T. B.*, Boyle, P. D., Petersen, J. L., Day, C. S.  Inorg. Chem. 200544, 8379-8390. DOI.org/10.1021/ic051074k

39. "Evidence for the Net Addition of Arene C-H Bonds across a Ru(II)-Hydroxide Bond" Feng, Y., Lail, M., Barakat, K. A., Cundari, T. R., Gunnoe, T. B.*, Petersen, J. L. J. Am. Chem. Soc. 2005127, 14174-14175. DOI.org/10.1021/ja054101e

38. "Ruthenium(II)-Mediated Carbon-Carbon Bond Formation between Acetonitrile and Pyrrole:  Combined Experimental and Computational Study" Pittard, K. A., Cundari, T. R., Gunnoe, T. B.*, Day, C. S., Petersen, J. L. Organometallics 200524, 5015-5024. DOI.org/10.1021/om0506668

37. "Developments in Catalytic Aromatic C-H Transformations: Promising Tools for Organic Synthesis" Goj, L., Gunnoe, T. B.* Curr. Org. Chem.20059, 671-685. DOI.org/10.2174/1385272053765051

36. "Reactions of (PCP)Ru(CO)(NHPh)(PMe3) (PCP = 2,6-(CH2PtBu2)2C6H3) with Substrates that Possess Polar Bonds" Zhang, J., Gunnoe, T. B.*, Petersen, J. L. Inorg. Chem. 200544, 2895-2907. DOI.org/10.1021/ic0483592

35. "Conversions of Ru(III) Alkyl Complexes to Ru(II) Complexes Through Ru-Calkyl Bond Homolysis" Lail, M., Gunnoe, T. B.*, Barakat, K. A., Cundari, T. R. Organometallics 200524, 1301-1305. DOI.org/10.1021/om049145v

34. "Reactions of TpRu(CO)(NCMe)(Me) (Tp = hydridotris(pyrazolyl)borate) with Heteroaromatic Substrates:  Stoichiometric and Catalytic C-H Activation" Pittard, K. A., Lee, J. P., Cundari, T. R., Gunnoe, T. B.*, Day, C. S., Petersen, J. L. Organometallics 200423, 5514-5523. DOI.org/10.1021/om049508r

33. "Experimental and Computational Studies of Ru(II) Catalyzed Addition of Aromatic C-H Bonds to Olefins" Lail, M., Bell, C. M., Conner, D., Cundari, T. R., Gunnoe, T. B.*, Petersen, J. L. Organometallics 200423, 5007-5020. DOI.org/10.1021/om049404g

32. "Ruthenium (II) Anilido Complex Containing a Bisphosphine Pincer Ligand: Reversible Formation of Amidinate Ligands via Intramolecular C-N Bond Formation" Zhang, J., Gunnoe, T. B.*, Boyle, P. D. Organometallics 2004, 23, 3094-3097. DOI.org/10.1021/om0497543

31. "Synthesis and Reactivity of a Coordinatively Unsaturated Ru(II) Parent Amido Complex:  Studies of X-H Activation (X = H or C)" Conner, D., Jayaprakash, K. N., Cundari, T. R., Gunnoe, T. B * Organometallics 2004, 23, 2724-2733. DOI.org/10.1021/om049836r

30. "Radical Polymerization of Styrene and Methyl Methacrylate with Ruthenium(II) Complexes" Arrowood, B. N., Lail, M., Gunnoe, T. B.*, Boyle, P. D. Organometallics 200322, 4692-4698. DOI.org/10.1021/om020871c

29. "Synthesis, Solid-State Crystal Structure, and Reactivity of a Monomeric Copper(I) Anilido Complex" Blue, E. D., Davis, A., Conner, D., Gunnoe, T. B.*, Boyle, P. D., White, P. S. J. Am. Chem. Soc. 2003125, 9435-9441. DOI.org/10.1021/ja0353659

28. "Octahedral Ru(II) Amido Complexes TpRu(L)(L')(NHR) (Tp = Hydridotris(pyrazolyl)borate; L = L' = P(OMe)3 or PMe3 or L = CO and L' = PPh3; R = H, Ph or tBu): Synthesis, Characterization and Reactions with Weakly Acidic C-H Bonds" Conner, D., Jayaprakash, K. N., Wells, M. B., Manzer, S., Gunnoe, T. B.*, Boyle, P. D. Inorg. Chem. 200342, 4759-4772. DOI.org/10.1021/ic034410a

27. "Addition of Arenes to Ethylene and Propene Catalyzed by Ruthenium" Lail, M., Arrowood, B. N., Gunnoe, T. B.* J. Am. Chem. Soc. 2003,125, 7506-7507. DOI.org/10.1021/ja035076k

26. "Computational Study of Methane Activation by TpRe(CO)2 and CpRe(CO)2 with a Stereoelectronic Comparison of Cyclopentadienyl and Scorpionate Ligands" Bergman, R. G., Cundari, T. R.*, Gillespie, A. M., Gunnoe, T. B., Harman, W. D., Klinckman, T. R., Temple, M. D., White, D. P. Organometallics 200322, 2331-2337. DOI.org/10.1021/om021048j

25. "Reaction of Ruthenium Benzylidene Complexes with Cyclic and Acyclic Imines: Oligomerization of 1-Pyrroline and Metathesis via Tautomerism" Zhang, J., Gunnoe, T. B.* Organometallics 200322, 2291-2297. DOI.org/10.1021/om0301029

24. "Ruthenium(II) Anilido Complexes TpRuL2(NHPh): Oxidative 4,4'-Aryl Coupling Reactions (Tp = Hydridotris(pyrazolylborate); L = PMe3, P(OMe)3 or CO)" Conner, D., Jayaprakash, K. N., Gunnoe, T. B.*, Boyle, P. D. Organometallics 2002, 21, 5265-5271. DOI.org/10.1021/om0206406

23. "Synthesis, Spectroscopy, and Solid-State Characterization of the Hexanuclear Copper Macrocycle Cu6Cl6(m-PCHP)6" Blue, E. D., Gunnoe, T. B.*, Brooks, N. R. Angew. Chem. Int. Ed. 200241, 2571-2573. DOI.org/10.1002/1521-3757(20020715)114:14<2683::AID-ANGE2683>3.0.CO;2-K

22. "Influence of the Filled dp-Manifold and L/L' Ligands on the Structure, Basicity and Bond Rotations of the Octahedral and d6 Amido Complexes TpRu(L)(L')(NHPh) (Tp = Hydridotris(pyrazolyl)borate; L = L' = PMeor P(OMe)3, or L = CO and L' = PPh3):  Solid-State Structures of [TpRu(PMe3)2(NH2Ph)][OTf], [TpRu{P(OMe)3}2(NH2Ph)][OTf], and     TpRu{P(OMe)3}2(NHPh)" Conner, D., Jayaprakash, K. N., Gunnoe, T. B.*, Boyle, P. D. Inorg. Chem. 200241, 3042-3049. DOI.org/10.1021/ic020163j

21. "Synthesis of the RuIV Amido Complex [TpRu(CO)(PPh3)(NHPh)][OTf]2 (Tp = hydridotris(pyrazolyl)borate; OTf = trifluoromethanesulfonate) and Deprotonation to Form an Octahedral and d4 Imido Complex:  Computational Study of RuIV-Imido Bonding" Jayaprakash, K. N., Gillespie, A. M., Gunnoe, T. B.*, and White, D. P.* Chemical Communications 20024, 372.  Correction: Chemical Communications 20024, 1650. DOI.org/10.1039/B110999E

20. "Synthesis and Reactivity of the Octahedral d6 Parent Amido Complexes TpRu(L)(L')(NH2) (Tp = Hydridotris(pyrazolyl)borate; L = L' = P(OMe)3, PMe3; L = CO and L' = PPh3) and [TpRu(PPh3)(NH2)2][Li]" Jayaprakash, K. N., Conner, D., Gunnoe, T. B.* Organometallics 200120, 5254-5256. DOI.org/10.1021/om010739x

19. "Preparation of the Octahedral d6 Amido Complex TpRu(CO)(PPh3)(NHPh) (Tp = Hydridotris(pyrazolyl)borate):  Solid-State Structural Characterization and Reactivity" Jayaprakash, K. N., Gunnoe, T. B.*, Boyle, P. D. Inorg. Chem. 200140, 6481-6486. DOI.org/10.1021/ic010785p

18. "Comparison of the Relative Electron-Donating Abilities of Hydridotris(pyrazolyl)borate and Cyclopentadienyl Ligands:  Different Interactions with Different Transition Metals" Tellers, D. M., Skoog, S. J., Bergman, R. G.*, Gunnoe, T. B., Harman, W. D. Organometallics 200019, 2428-2432. DOI.org/10.1021/om000043o

 

Publications from graduate and postdoctoral work:

17. "Binding and Activation of Aromatic Molecules by a Molybdenum p-Base" Meiere, S. H., Keane, J. M., Gunnoe, T. B., Sabat, M., Harman, W. D.* J. Am. Chem. Soc. 2003125, 2024-2025. DOI.org/10.1021/ja021057j

16. "Ligand-Modulated Stereo- and Regioselective Tandem Addition Reactions of Rhenium-Bound Naphthalene" Valahovic, M. T., Gunnoe, T. B., Sabat, M., Harman, W. D.* J. Am. Chem. Soc. 2002124, 3309-3315. DOI.org/10.1021/ja012066f

15. "Interfacial and Intrafacial Linkage Isomerizations of Rhenium Complexes with Aromatic Molecules" Brooks, B. C., Meiere, S. H., Friedman, L. A., Carrig, E. H., Gunnoe, T. B., Harman, W. D.* J. Am. Chem. Soc. 2001123, 3541-3550. DOI.org/10.1021/ja003195j

14. "Dihapto Coordination of Aromatic Molecules by the Asymmetric p-Bases {TpRe(CO)(L)} (Tp = hydridotris(pyrazolyl)borate; L = tBuNC, PMe3, pyridine, 1-methylimidazole, or NH3)" Meiere, S. H., Brooks, B. C., Gunnoe, T. B., Carrig, E. H., Sabat, M., Harman, W. D.*Organometallics 200120, 3661-3671. DOI.org/10.1021/om010227i

13. "A Promising New Dearomatization Agent:  Crystal Structure, Synthesis, and Exchange Reactions of the Versatile Complex TpRe(CO)(1-methylimidazole)(h2-benzene) (Tp = Hydridotris(pyrazolyl)borate)" Meiere, S. H., Brooks, B. C., Gunnoe, T. B., Sabat, M., Harman, W. D.*Organometallics 200120, 1038-1040. DOI.org/10.1021/om000900o

12.  "{TpRe(bpy)}: A Novel Pentaaminerhenium System that Stabilizes High and Low Oxidation States (Tp = Hydridotris(pyrazolyl)borate; bpy = 2,2'-Bipyridyl)" Gunnoe, T. B., Meiere, S. H., Sabat, M., Harman, W. D.* Inorg. Chem. 200039, 6127-6130. DOI.org/10.1021/ic000707m

11. "Stereoselective Dihapto-Binding of Prochiral Aromatic Compounds by {TpRe(CO)(PMe3)}: Synthesis, Characterization, Stability, and Enantiofacial Discrimination (Tp = Hydrido(tris)pyrazolylborate)" Gunnoe, T. B., Sabat, M., Harman, W. D.* Organometallics 200019, 728-740. DOI.org/10.1021/om9906722

10. "Dihapto Binding of Aromatic Molecules by p-Basic Transition Metal Complexes:  Development of Alternatives to the {Os(NH3)5}2+ Fragment" Brooks, B. C., Gunnoe, T. B., Harman, W. D.* Coord. Chem. Rev. 2000206-207, 3-61. DOI.org/10.1016/S0010-8545(99)00249-0

9.  "Enantiofacial Discrimination in Dihapto-Coordination of Aromatic Molecules by the Chiral p-Base/s-Lewis Acid {TpRe(CO)(PMe3)}" Gunnoe, T. B., Sabat, M., Harman, W. D.* J. Am. Chem. Soc. 1999121, 6499-6500. DOI.org/10.1021/ja990891e

8.  "Rhenium(I) Terpyridine p-Bases:  Reversible h2-Coordination of Ketones, Aldehydes, and Olefins in the Terpyridine Plane" Helberg, L. E., Gunnoe, T. B., Brooks, B. C., Sabat, M., Harman, W. D.* Organometallics 199918, 573-581. DOI.org/10.1021/om980500p

7. "Reactions of TpRe(CO)2(THF) with Aromatic Molecules (Tp = Hydridotris(pyrazolyl)borate)" Gunnoe, T. B., Sabat, M., Harman, W. D.* J. Am. Chem. Soc. 1998120, 8747-8754. DOI.org/10.1021/ja980690v

6.  "Spectra, Structure, Ligand Exchange, and Decomposition of a Tungsten(II) Ether Complex" Gunnoe, T. B., Caldarelli, J. L., White, P. S., Templeton, J. L.* Angew. Chem. Int. Ed. 199837, 2093-2096. DOI.org/10.1002/(SICI)1521-3773(19980817)37:15<2093::AID-ANIE2093>3.0.CO;2-T

5.  "Synthesis and Reactivity of Tungsten(II) Methylene Complexes" Gunnoe, T. B., Surgan, M., White, P. S., Templeton, J. L.*, Casarrubios, L.Organometallics 199716, 4865-4874. DOI.org/10.1021/om970470a

4.  "Reaction of a Tungsten(II) Methylene Complex with Excess Base To Form a C3H5-Bridged Dimer" Gunnoe, T. B., White, P. S., Templeton, J. L.* Organometallics 199716, 3794-3799. DOI.org/10.1021/om970271r

3.  "Electrophilic Tungsten (II) Methylene Carbene Complexes:  Adduct Formation, Methylene Transfer, and Catalysis of Aziridine Formation from Imines and Ethyl Diazoacetate" Gunnoe, T. B., White P. S., Templeton, J. L.*, Casarrubios, L. J. Am. Chem. Soc. 1997119, 3171-3172. DOI.org/10.1021/ja9640206

2.  "Synthesis and Deprotonation/Alkylation Reactions of the Chiral Carbene Complex Tp'(CO)(NO)Mo=C(OMe)(Me)" Gunnoe, T. B., White, P. S., Templeton, J. L.* Organometallics 199716, 370-377. DOI.org/10.1021/om960593f

1.  "Stepwise Oxidation of Benzylamine Coordinated to the [Tp'W(CO)(PhC2Me)]+ Moiety" Gunnoe, T. B., White, P. S., Templeton, J. L.* J. Am. Chem. Soc. 1996118, 6916-6923. DOI.org/10.1021/ja953944a